The pH scale: acids, alkalis and neutral solutions
The pH scale runs from 0 to 14 and measures how acidic or alkaline a solution is. A pH of 7 is neutral. Acids have a pH below 7, and alkalis have a pH above 7. The higher the concentration of hydrogen ions, the lower the pH. You can measure pH with universal indicator or a pH probe.
Reading the scale
Tap a number on the scale to see what that pH tells you. There are three zones:
- pH 0 up to just under 7: acidic
- pH 7: neutral
- just over 7 up to pH 14: alkaline
An acid makes hydrogen ions, written H⁺, when it dissolves in water. An alkali in water gives hydroxide ions, written OH⁻. A base is any substance that reacts with an acid to give a salt and water only. Edexcel defines an alkali as a base that dissolves in water.
Each step on the scale is ten times bigger
Each whole number on the scale is a big jump in acidity. When the hydrogen ion concentration goes up ten times, the pH goes down by 1. So a solution at pH 3 has ten times the hydrogen ion concentration of one at pH 4, and 100 times that of one at pH 5.
Edexcel and both OCR courses state this rule too. AQA marks it as Higher tier content. AQA and OCR Gateway both keep pH to whole numbers for this work. Pick two points on the scale widget to see the factor between them.
Measuring pH
Universal indicator changes colour to show roughly where a solution sits on the scale. AQA also calls it a wide range indicator, and says it gives an approximate pH. A pH probe or pH meter gives a reading as a number. OCR Gateway names both indicator and meter.
Edexcel also names three single indicators: litmus, methyl orange and phenolphthalein. It lists the effect of acids and alkalis on each one. KS3 science covers the pH scale and indicators without naming any.
Neutralisation
An acid and an alkali react to make a salt and water. This is neutralisation. The hydrogen ions from the acid join the hydroxide ions from the alkali to make water: H⁺(aq) + OH⁻(aq) → H₂O(l). Writing ionic equations like this one yourself is Higher tier on AQA, Edexcel and OCR Gateway.
The acid decides the family of salt. AQA gives the pattern: hydrochloric acid makes chlorides, nitric acid makes nitrates and sulfuric acid makes sulfates. Acids also react with some metals to make a salt and hydrogen, so the reactivity series matters here too. With a metal carbonate, AQA says you get a salt, water and carbon dioxide. The page on tests for gases shows how to check for both gases.
Strong, weak, dilute and concentrated
These four words sound alike, and they describe two different things. Strong and weak are about how much of the acid splits into ions in water. A strong acid splits up completely. A weak acid only partly splits up. Dilute and concentrated are about how much acid is in a set volume of water.
AQA gives hydrochloric, nitric and sulfuric acids as strong acids, and ethanoic, citric and carbonic acids as weak ones. At the same concentration, the stronger acid has the lower pH. AQA places this in Higher tier. OCR Twenty First Century adds that a weak acid reacts less than a strong acid of the same concentration.
Common mistakes
- Using strong to mean concentrated. OCR says learners often mix these up. Strength is about splitting into ions, and concentration is about how much acid there is.
- Treating each step on the scale as the same size. One step down means ten times the hydrogen ion concentration.
- Assuming an alkali is safer than an acid. OCR lists this belief as a common misconception.
- Calling every base an alkali. An alkali is a base that dissolves in water.
Sort solutions along the scale and build neutralisations in pH Detective. The chemistry hub lists the other pages in this set.
Questions people ask
Is pH 7 always neutral?
On the scale used at GCSE and KS3, yes. A solution with a pH of 7 is neither acidic nor alkaline.
Is the ten times rule on KS3?
No. KS3 covers the pH scale and indicators. Hydrogen ions and the ten times rule start at GCSE.
What salt does sulfuric acid make?
A sulfate. The metal in the base, alkali or carbonate gives the first part of the name, so zinc oxide and sulfuric acid make zinc sulfate.